曹劍瑜

教授曹劍瑜
Email:  jycao@cczu.edu.cn; jyucao@hotmail.com

教育經(jīng)歷:

2006/09 – 2009/07, 中科院上海微系統與信息技術(shù)研究所, 材料物理與化學(xué), 博士

2001/09 – 2004/07, 南京師范大學(xué)化學(xué)與環(huán)境科學(xué)學(xué)院, 物理化學(xué), 碩士

工作經(jīng)歷：

2009/07 – 至今, 常州大學(xué)石油化工學(xué)院, 講師(2006) 副教授(2011) 教授(2017) 博士生導師(2018)

2019/01 – 2019/12, 澳大利亞昆士蘭大學(xué)生物工程與納米技術(shù)研究所, 訪(fǎng)問(wèn)學(xué)者

2013/08 – 2014/08, 美國特拉華(Delaware)大學(xué)化學(xué)工程與分子工程系, 訪(fǎng)問(wèn)學(xué)者

榮譽(yù)與獲獎：

江蘇省高校“青藍工程”中青年學(xué)術(shù)帶頭人(2019)

常州市自然科學(xué)論文三等獎(2019)

國家公派出國留學(xué)基金(2018)

常州市自然科學(xué)論文三等獎(2015)

江蘇省高校“青藍工程”中青年骨干教師(2014)

江蘇省教育廳公派留學(xué)基金(2013)

常州市自然科學(xué)論文二等獎(2011)

江蘇省企業(yè)博士人才項目(2011)

中國石油和化學(xué)工業(yè)協(xié)會(huì )(CPCIA)科技進(jìn)步獎三等獎(2010)

常州市“831高層次創(chuàng )新創(chuàng )業(yè)人才培養工程”首批中青年骨干人才(2009)

中國科學(xué)院所長(cháng)獎(2009)

社會(huì )兼職（社會(huì )兼職填是否擔任過(guò)專(zhuān)業(yè)雜志編委、專(zhuān)業(yè)委員會(huì )委員、專(zhuān)業(yè)協(xié)會(huì )會(huì )員等）

中國化學(xué)會(huì )會(huì )員、國家基金委函評專(zhuān)家。

研究方向:

有機液流電池、新型二次電池、納米電催化

科研項目:

[1]國家自然科學(xué)基金面上項目(21975033): 基于氧化還原活性共價(jià)有機框架聚合物的水系全有機二次電池設計(2020-2023), 66萬(wàn), 主持, 在研.

[2]國家自然科學(xué)基金面上項目(21573025): 基于醌類(lèi)衍生物電化學(xué)的全有機水系液流電池高電位電解質(zhì)研究(2016-2019), 66萬(wàn), 主持, 結題.

[3]國家自然科學(xué)基金青年基金項目(21103014):直接甲醇燃料電池石墨烯基擴散層電極及傳質(zhì)機理研究(2012-2014), 主持, 結題.

[4]江蘇省自然科學(xué)基金項目(BK2012591):石墨烯負載金屬氫氧化物/石墨烯不對稱(chēng)電化學(xué)電容器研究(2013-2014), 主持, 結題.

[5]江蘇省企業(yè)博士集聚計劃項目(2011Z0062)：直接甲醇燃料電池膜電極的有序結構設計與性能研究(2011-2013), 主持, 結題.

[6]江蘇省太陽(yáng)能電池材料與技術(shù)重點(diǎn)實(shí)驗室開(kāi)放課題(201106): 有序碳基復合儲能材料的制備及其電極動(dòng)力學(xué)機理研究(2012-2013), 主持, 結題.

研究論文(2017-2023)

1. Yanjun Shi*, Pengcheng Wang, Haiguang Gao, Wei Jin, Yanli Chen, Yucheng Huang, Tai-Rui Wu, De-Yin Wu, Juan Xu, Jianyu Cao(曹劍瑜)*, π-Conjugated N-heterocyclic compound with redox-active quinone and pyrazine moieties as a high-capacity organic cathode for aqueous zinc-ion batteries, Chem. Eng. J., 2023, 461, 141850.

2. Xue Xia,? Mengna Qin,? Yang Sun, Yanjun Shi, Juan Xu,* Yong-Miao Shen,* Dengfeng Guo, Zhidong Chen, Jianyu Cao(曹劍瑜)*, A high-capacity 1,2:3,4-dibenzophenazine anode integrated into carbon felt for an aqueous organic flow battery in alkaline media, Green Chem., 2022, 24, 8783-8790.

3. Caixing Wang,? Yanrong Wang,? Meng Tao,? Bo Yu, Kaiqiang Zhang, Jie Wei, Yuzhu Liu, Pengbo Zhang, Guochun Ding, Zuoxiu Tie*, Jianyu Cao(曹劍瑜)*, Zhong Jin*, Highly water-soluble 6-quinoxalinecarboxylic acid for high-voltage aqueous organic redox flow batteries, ACS Appl. Energy Mater., 2022, 5, 10379-10384.

4. Chuan-Wei Feng, Dan-Yan Wang, Hui-Ling Lu, Zi-Wei Xi, Yong-Miao Shen*, Jianyu Cao(曹劍瑜)*, Photocatalytic synthesis of sulfinamides and sulfoxides from nitroarenes and thiophenols, Org. Lett., 2022, 24, 4485-4489.

5. Wenfei Zhang, Yanli Chen*, Tai-Rui Wu, Xue Xia, Juan Xu, Zhidong Chen, Jianyu Cao(曹劍瑜)*, De-Yin Wu, Computational design of phenazine derivative molecules as redox-active electrolyte materials in alkaline aqueous organic flow batteries, New J. Chem., 2022, 46, 11662-11668.

6. Hongchao Zhang,? Qinghong Huang,? Xue Xia, Yanjun Shi, Yong-Miao Shen, Juan Xu,* Zhidong Chen and Jianyu Cao(曹劍瑜)*, Aqueous organic redox-targeting flow battery based on Nernstian-potential-driven anodic redoxtargeting reactions, J. Mater. Chem. A, 2022, 10, 6740-6747.

7. Zirui Liu,? Zheng Wang,? Yanjun Shi, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu* and Jianyu Cao(曹劍瑜)*, A high-capacity hexaazatrinaphthylene anode for aqueous organic hybrid flow batteries, J. Mater. Chem. A, 2021, 9, 27028-27033.

8. Jun Qiao, Zirui Liu, Zheng Wang, Meng Qin, Yanjun Shi, Juan Xu,* Zhidong Chen, and Jianyu Cao(曹劍瑜)*, Long-life aqueous H⁺/K⁺ dual-cation batteries based on dipyridophenazine//hexacyanoferrate electrodes, ACS Appl. Energy Mater. 2021, 4, 4903-4909.

9. Jun Qiao, Meng Qin, Yong-Miao Shen, Jianyu Cao(曹劍瑜),* Zhidong Chen and Juan Xu*, A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode, Chem. Commun., 2021, 57, 4307-4310.

10. Jianyu Cao(曹劍瑜), Junya Tian, Juan Xu* and Yonggang Wang*, Organic flow batteries: recent progress and perspectives, Energy & Fuels 2020, 34, 11, 13384-13411.

11. Wenbo Zhou, Wenjie Liu, Meng Qin, Zhidong Chen, Juan Xu*, Jianyu Cao(曹劍瑜)* and Jun Li*, Fundamental properties of TEMPO-based catholytes for aqueous redox flow batteries: effects of substituent groups and electrolytes on electrochemical properties, solubilities and battery performance, RSC Adv., 2020, 10, 21839-21844.

12. Yang Zhang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Juan Xu* and Chengzhong Yu, An organic-based aqueous hybrid flow battery with high power and long cycle life: tetrapyridophenazine/ferrocyanide system, J. Mater. Chem. A, 2020, 8, 6874-6881.

13.Binbin Wang, Yang Zhang, Ye Zhu, Yong-Miao Shen, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹劍瑜)*, Juan Xu*, Redox-active poly (6-(1H-pyrrol-1-yl) quinoxaline) as a novel organic anode material for aqueous hybrid flow batteries, J. Power Sources, 2020, 451, 227788.

14.Yang Zhang, Wenjie Liu, Zheng Wang, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu*, Jianyu Cao(曹劍瑜)*, Tetrapyridophenazine/graphene composites for aqueous hybrid flow battery anodes with long cycle life, Carbon, 2020, 161, 309-315.

15. Xiaolin Li, Yongsheng Zhou, Yingying Du, Juan Xu*, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹劍瑜)*, PtCu nanoframes as ultra-high performance electrocatalysts for methanol oxidation, Int. J. Hydrogen Energy, 2019, 44, 18050-18057.

16. Jianyu Cao(曹劍瑜), Fanfan Ding, Hongping Chen, Hongning Wang, Wenchang Wang, Zhidong Chen*, Juan Xu*, A new redox-active conjugated polymer containing anthraquinone pendants as anode material for aqueous all-organic hybrid-flow battery, J. Power Sources, 2019, 423, 316-322.

17. Juan Xu, Huada Cao, Chaoying Ni, Yan Wang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Design and synthesis of sandwich-like CoNi₂S₄@C@NiCo-LDH microspheres for supercapacitors, J. Solid State Electrochem., 2019, 23, 1513-1522.

18.Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao(曹劍瑜)*, Zhidong Chen*, Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors, J. Appl. Electrochem., 2019, 1-12.

19. Mingming Dong, Hongping Chen, Juan Xu*, Zhidong Chen* and Jianyu Cao(曹劍瑜)*, Synthesis of Cu-decorated PtTe nanotubes with high electrocatalytic activity for oxygen reduction, J. Alloy. Compd., 2019, 770, 76-81.

20. Jianyu Cao(曹劍瑜), Meng Tao, Hongping Chen, Juan Xu*, Zhidong Chen*, A highly reversible anthraquinone-based anolyte for alkaline aqueous redox flow batteries, J. Power Sources, 2018, 386, 40-46.

21. Jianyu Cao(曹劍瑜), Yingying Du, Mingming Dong, Zhidong Chen*, Juan Xu*, Template-free synthesis of chain-like PtCu nanowires and their superior performance for oxygen reduction and methanol oxidation reaction, J. Alloy. Compd., 2018, 747, 124-130.

22. Jianyu Cao(曹劍瑜), Xiaodi Jia, Mengwei Guo, Yingying Du, Juan Xu* and Zhidong Chen*, Fe–N co-decorated hierarchically porous graphene as a highly efficient electrocatalyst for the oxygen reduction reaction, Sustain. Energ. Fuels, 2017, 2, 169-174.

23. Jianyu Cao(曹劍瑜), Zhentao Zhu, Juan Xu*, Meng Tao and Zhidong Chen*, Nitrogen-doped porous graphene as a highly efficient cathodic electrocatalyst for aqueous organic redox flow battery application, J. Mater. Chem. A, 2017, 5, 7944–7951.

24. Jianyu Cao(曹劍瑜), Yue Hu, Lijuan Chen, Juan Xu*, Zhidong Chen*, Nitrogen-doped carbon quantum dot/graphene hybrid nanocomposite as an efficient catalyst support for the oxygen reduction reaction, Int. J. Hydrogen Energy, 2017, 42, 2931-2942.

25. Juan Xu, Chaojie Ma, Jianyu Cao(曹劍瑜)* and Zhidong Chen*, Facile synthesis of core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides as high-performance electrode materials for supercapacitors, Dalton Transactions, 2017, 46, 3276–3283.

26. Juan Xu, Kexing Hou, Zhengwei Ju, Chaojie Ma, Wenchang Wang, Cheng Wang, Jianyu Cao(曹劍瑜)* and Zhidong Chen*, Synthesis and Electrochemical Properties of Carbon Dots/Manganese Dioxide (CQDs/MnO₂) Nanoflowers for Supercapacitor Applications, J. Electrochem. Soc., 2017, 164(2), A430-A437.

授權專(zhuān)利

[1]一種鋰離子電池負極材料及其制備方法(授權), 中國發(fā)明專(zhuān)利,CN201310147107.4(2014)

[2]一種磷酸鐵鋰-碳-二氧化硅復合材料及其制備方法(授權), 中國發(fā)明專(zhuān)利,201210382917.3(2014)

[3]一種碳載Co核-Pt殼納米粒子催化劑及其制備方法(授權),中國發(fā)明專(zhuān)利,CN 201310524211.0(2015)(已轉讓)

[4]基于吡嗪多羧酸配體構筑金屬錳有機框架化合物的方法及應用(授權), 中國發(fā)明專(zhuān)利,201811090629.4(2021)

[5]混合液流電池陰極用TEMPO基聚吡咯及制備方法(授權), 中國發(fā)明專(zhuān)利, 202010064852.2 (2021) (已轉讓)

[6]單晶硅太陽(yáng)能電池表面處理用制絨劑及使用方法(授權), 中國發(fā)明專(zhuān)利,201110177294.1 (2014)

[7]高導電性柔性石墨烯膜電極的制備方法(授權), 中國發(fā)明專(zhuān)利,201310243138.X (2015)

[8]一種超級電容器用鎳鈷雙氫氧化物/含氮碳納米角復合材料及其制備方法(授權), 中國發(fā)明專(zhuān)利,201610414633.6(2018)

[9]一種有機電解液體系不對稱(chēng)電化學(xué)電容器及其制備方法(授權), 中國發(fā)明專(zhuān)利,201310350232.5(2015) (轉讓)

[10]一種含氮碳量子點(diǎn)/石墨相氮化碳復合光催化劑的制備方法(授權), 中國發(fā)明專(zhuān)利,201710497252.3(2019)

[11]一種基于金屬有機配合物液流正極的水系單液流電池及其制備方法(授權), 中國發(fā)明專(zhuān)利,201710578191.3(2019)

[12]一種以碳納米角/聚酰亞胺復合物為固體負極的鄰菲羅啉鐵配合物-水系半液流電池(授權), 中國發(fā)明專(zhuān)利,201811157300.5 (2021)(獨占許可)

[13]基于含氧化還原活性側基單元的共軛微孔聚合物負極的水系全有機混合液流電池(授權), 中國發(fā)明專(zhuān)利,202011355637.4 (2021)(獨占許可)

[14]基于電活性吩嗪衍生物負極的堿性水系混合液流電池(授權), 中國發(fā)明專(zhuān)利,202011380434.0 (2021)(獨占許可)

[15]一種COF負載的金屬氫氧化物電極的制備方法及其應用(授權), 中國發(fā)明專(zhuān)利,201910619326.5 (2021)

[16]一種基于吡啶基吩嗪的高功率長(cháng)壽命的中性水系混合液流電池(授權), 中國發(fā)明專(zhuān)利, 201911195708.6 (2022)(獨占許可)

[17]一種基于聚吡咯喹喔啉負極的全水系混合液流電池及制備方法(授權), 中國發(fā)明專(zhuān)利, 201911073961.4 (2022)(獨占許可)

[18]基于具有多種氧化態(tài)嗪類(lèi)化合物的水系全有機二次電池(授權), 中國發(fā)明專(zhuān)利, 202110589675.4 (2022)